Sender dependent transport mappings
The optional sender dependent addresses file allows the relay host for for outgoing SMTP connections to be set on a per-address or per-domain basis. The left hand side of each entry can be either a full email address like foo@bar.com, or just a domain like @bar.com.

The right hand side must be in the format transport:nexthop. In the typical case where you want to relay mail via a specific mail server, transport should be smtp and nexthop the hostname or IP address of the mail server.